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Phosphorous acid, H 3 PO 3 , is oxidized to phosphoric acid, H ... | Filo
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Under the influence of oxidizing agents, hypophosphorous acid is transformed into phosphorous acid: H3 PO2 oridiring agent ⟶ H3 PO3 The kinetics of this transformation present the following features. At a low concentration of oxidizing agent, rH3 PO3=k[ oxidizing agent ][H3 PO2] At a high concentration of oxidizing agent, rH3 PO3=k^'[H^ ][H3 PO2] To explain the observed kinetics, it has been postulated that, with hydrogen ions as catalyst, normal unreactive H3 PO2 is transformed reversibly into
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