Sigma-Aldrich - 244511 Page 2 of 14 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada

Product and Company Identification. Product Name: TOLUOL Product Code: 1460N Savogran Company 259 Lenox St PO Box 130 Norwood, MA 02062-0130 Information Phone: 781-762-5400 Emergency Phone: 800-424-9300 Website Address: www.savogran.com Synonyms: 405001, 405006, Toluene Product Use: SOLVENT/THINNER. 2. Hazards Identification GHS Ratings:

Toluene Revision Date 25-Dec-2021 Component CAS No IARC NTP ACGIH OSHA Mexico Toluene 108-88-3 Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Not mutagenic in AMES Test Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals. Developmental Effects Developmental effects have occurred in experimental animals.

Common Names: Toluol, Methyl Benzene, Phenylmethane. California Proposition 65: This product contains Toluene and may contain trace amounts of Benzene, a chemical known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65.

Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 01.31.2015 Page 3 of 8 Toluene, Reagent Grade NFPA SCALE {0-4)

Product: Toluol M ex (ID no. 30857804/SDS_GEN_00/EN) Date of print 04.03.2025 Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A) Suitable

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. None generally recognized. For complete discussion of toxicology data refer to Section 11. Flush eyes with large amounts of water for 15 minutes.

Synonyms toluol; phenyl methane; methyl benzene; benzene, methyl- See section 16 for complete information. Recommended use This product is intended for use as a refinery feedstock, fuel or for use in engineered processes.

Substance information for UN 1294 - Toluene based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials.

Toluol ≥99,5 %, zur Synthese Artikelnummer: 9558 Deutschland (de) Seite 2 / 22 ABSCHNITT 2: Mögliche Gefahren 2.1 Einstufung des Stoffs oder Gemischs Einstufung gemäß Verordnung (EG) Nr. 1272/2008 (CLP) Ab-schnitt Gefahrenklasse Katego-rie Gefahrenklasse und -kategorie Gefahren-hinweis 2.6 Entzündbare Flüssigkeiten 2 Flam. Liq. 2 H225