
Reversible formation of coordination bonds in Sn-based metal …
May 25, 2021 · Here, we apply a metal-organic framework (MOF) chemistry between Sn-nodes and lithium active ligands to create two Sn-based MOFs comprising Sn 2 (dobdc) and Sn 2 (dobpdc) with extended...
Structural reconstruction of Sn-based metal–organic frameworks …
Mar 1, 2022 · Herein, a series of six N coordinated Sn-based metal-organic frameworks (Sn-N6-MOFs) are newly developed for electrochemical CO 2 reduction (CO 2 RR). 2% Sn-N6-MOF achieves the optimal catalytic performance with a formate Faradaic efficiency of ∼85% and a current density of 23 mA·cm −2 at −1.23 V vs. RHE.
Litchi-like Sn-MOF derived SnS2@SC composite as an advanced …
In this study, a lyotropic Sn-MOF was synthesized using tin sulfate and terephthalic acid as the tin source and organic ligand. The lychee-like Sn-MOF was then utilized as a precursor to prepare a hollow porous SnS 2 @SC composite containing S-doped carbon through a …
Preparation of promising anode materials with Sn-MOF as …
Nov 25, 2020 · SnO@C, Sn/SnO@C and Sn@C were synthesized by One-step reduction method using Sn-MOF as both the precursor and the sacrificing template. SnO and Sn are embedded in a carbon matrix uniformly in the form of nanorods and nanospheres, respectively.
MOFs and their derivatives as Sn-based anode materials for lithium ...
Nov 5, 2021 · In this review, we mainly summarize the structural features, energy storage mechanism, and recent advances in the rational design and preparation of Sn-MOFs and MOF-derived Sn-based composites for LiB and SIB anodes, and current challenges and future directions for further development are discussed.
In-modified Sn-MOFs with high catalytic performance in formate ...
Aug 1, 2023 · Electrochemical reduction of carbon dioxide (CO2ER) has become an effective solution to relieve the energy crisis and tackle climate change. In this study, a series of tin-based organic frameworks modified by In (Sn-MOF/Inx) were successfully synthesized via a simple hydrothermal method and explored for high
Sulfur-doping tunes p-d orbital coupling over asymmetric Zn-Sn …
Mar 5, 2025 · Here, we show a ligand co-etching approach to create asymmetric Zn-Sn dual-atom sites (DASs) within metal-organic framework (MOF)-derived yolk-shell carbon frameworks (named Zn 1 Sn 1 /SNC).
High-performance Sn-based metal-organic frameworks anode …
Dec 13, 2019 · Here, Sn-based MOFs anode materials with different morphologies are prepared by two different flexible and controllable methods, reflux method (named as reflux Sn-MOF), and hydrothermal method (named as hydrothermal Sn-MOF).
Sn-MOFs/G composite materials for long cycling performance
Jan 16, 2022 · In this paper, the Sn-MOFs/G was synthesized by a simple one-step precipitation. The Sn-MOFs/G samples can enhance electronic conductivity evidently and electrochemical properties as the anode for lithium ion batteries (LIBs) compared to Sn-MOFs.
Sn(101) Derived from Metal–Organic Frameworks for Efficient ...
Jun 16, 2021 · A metal–organic framework (MOF) precursor Sn-MOF has been carbonized and then etched to successfully fabricate Sn (101)/SnO 2 /C composites with good control of the carbonization time and the concentration of hydrochloric acid.