New protocol streamlines preparation of alcohol-containing synthetic intermediates and bioactive compounds
Given that alcohol is the most frequent functional group found in bioactive natural products and marketed drugs, and is a ...
Discovery of high-spin manganese centers sheds light on photosynthesis
In a small manganese oxide cluster, teams from HZB and HU Berlin have discovered a particularly exciting compound: two high-spin manganese centers in two very different oxidation states. This complex ...
C&EN3d
Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anti-Markovnikov Oxidation of Alkenes
Department of Chemistry, New York University, 24 Waverly Place, 3rd Floor, New York, New York 10003, United States ...
C&EN21d
Dibenzothiophenium Salts: Practical Alternatives to Hypervalent I(III)-Based Reagents
You are free to share (copy and redistribute) this article in any medium or format and to adapt (remix, transform, and build upon) the material for any purpose, even commercially within the parameters ...
Frontiers20d
Challenges and perspectives in using unspecific peroxygenases for organic synthesis
Such examples are inspiring to continuously expand the applications of UPOs in organic synthesis. UPOs efficiently catalyze a wide range of oxidation reactions. Their broad substrate scope and mild ...