After completion, students should be able to identify key disconnections of pericyclic reactions (specifically [4+2] and [2+2] cycloadditions, as well as [3,3]-sigmatropic rearrangements) for the ...

and a new reaction mechanism—diboron-participated [3,3]-sigmatropic rearrangement. A library of chiral vicinal diamines, most otherwise inaccessible, is efficiently built that can be applied as chiral ...